Class XI Chemistry

CBSE Class 11 Study Materials

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CH 1 Some basic concepts of chemistry

CH 2 Structure of Atom

CH 3 classification of elements

CH 4 chemical bonding and molecular structure

CH 5 states of matter

CH 6 Thermodynamics

CH 7-Equilibrium

CH 8-Redox -Reaction

CH 9 Hydrogen

CH 10 S-Block

CH 11 The p block element

CH 12 Organic Chemistry

CH 13 Hydrocarbons

CH 14 Environmental Chemistry

 

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Class XI Chemistry Practice Paper

Central Board of Secondary Education

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CHEMISTRY

CLASS-XI

Time Allowed: 3 hours Maximum Marks: 70

 

General Instructions:

I) All questions are compulsory.

ii) Question number 1 to 8 are short answer questions and carry 1mark each.

iii) Question number 9 to 18 are short answer questions and carry 2 marks each.

iv) Question number 19 to 27 are also short answer questions and carry 3 marks each.

v) Question number 28 to 30 are long answer questions and carry 5 marks each.

vi) Use log tables if necessary

1. Write the electronic configuration of Fe3+ ion (Atomic number of Iron = 26).

2. Why does boron form electron deficient compounds?

3. Tertiary carbocation is more stable than Secondary. Explain why?

4. How does molarity change with temperature?

5. Write the IUPAC name of tertiary butyl alcohol.

6. An atomic orbital has l=2.What are the possible values of m?

7. Find out the oxidation number of manganese in MnO4 and MnO42-.

8. Carbon shows the property of catenation remarkably. Assign a reason for this statement.

9. Write any two points of differences between sigma and pi bond.

OR

a) How many sigma and pi bond are present in the molecule:

CH2=CH-CH=CH2.

b) Which type of hybrid orbital is used by the second carbon atom in the following molecule.

CH≡C-CH2-CH=CH2

10. What is the density of SO2 gas at 27oC. (Atomic Weights: S=32, O=16, R=0.0821l/K/mol.

11. What happens when

a) Lead sulphide is reacted with hydrogen peroxide solution.

b) Chlorine reacts with milk of lime. Write chemical equations for reactions involved.

12. Why do real gases deviate from the ideal behaviour? What are the conditions under which real gases show ideal behaviour?

13. The mass of an electron is 9.1×10-31 Kg. If its kinetic energy is 3×10-25 J, calculate its wavelength.

14. Account for the following

a. The first ionization enthalpy of Mg is greater than that of Al.

b. Oxygen has a lower electron gain enthalpy than sulphur.

15. Calculate the bond order of O2+ and O22- molecular ions and predict their magnetic behaviour.

16. Explain the following:

a. Wurtz reaction

b. Huckles Rule

17. Account for the following :

a. Pentane has higher melting point than 2-methyl butane.

b. Ethyne is more acidic than ethane.

18. What are electrophiles and neucleophiles? Give one example of each.

19. Write the net ionic equation for the reaction of potassium dichromate(VI) with sodium sulphite in an acid solution to give chromium(III) ion and the sulphate ion.

OR

Permanganate (VII) ion in basic solution oxidises iodide ion to produce iodine and manganese dioxide. Write a balanced ionic equation to represent this redox reaction.

20. Write short notes on :

a. Photochemical Smog

b. Ozone Hole

c. Acid Rain

21. a. How will you prepare hydrogen peroxide by industrial method.

b. What happens when

i. ionic hydrides are treated with water?

ii. Boron tri-fluoride reacts with sodium hydride?

22. a. Define the term conjugate acid-base pair.

b. The value of Kc for the reaction 2A↔B+C is 2×10 -3 at 500K at a given time. The composition if reaction mixture is [A]=[B]=[C]= 3×10-4 M. Is the reaction mixture at equilibrium? If not, what is the direction of net reaction?

23. State Le-Chatelier’s Principle. What are its applications in the manufacture of Ammonia in Habers Process?

24. How will you detect the presence of nitrogen in Lassaigne’s Test .

During estimation of nitrogen by kjeldahl’s method the ammonia evolved from 0.5g of the compound neutralised 10ml of 1M H2SO4.Find out the percentage of nitrogen in the compound.

25. Draw the structure of:

a. Di-borane

b.AlCl3

C.BeCl2 in solid state

26. a. What do you understand by common ion effect?

b. Determine the solubility of barium sulphate in 0.05M in barium chloride solution.(Ksp-BaSO4=1.1×10-10).

27. Why lithium shows anomalous behaviour in the group. Give two points of similarities between lithium and magnesium.

28. Explain the following with suitable examples:

a. Inductive Effect.

b. Resonance Effect.

c. Hyper-conjugation.

OR

Define Isomerism. Explain the type of isomerism shown by

a. But-2-ene.

b. Conformations of Ethane.

29. a. SiF6 2- is known where as SiCl6 2- is not. Give possible reason.

b. Why is boric acid considered as a weak acid?

c. What are silicones?

d. CCl4 does not hydrolyse unlike SiCl4.

e. Tl(1) compounds are more stable than Al(1) compounds. Give reasons.

OR

a. Why does BCl3 act as a Lewis acid?

b. What is dry-ice? Why is it so called?

c. What is water gas? How is it prepared?

d. Which is the basic building unit of all silicates?

e. What are zeolites?

30. How will you bring about the following conversions?

i. Propene to 1- bromo-propane.

ii. Benzene to acetophenone.

iii.Ethyne to acetaldenhyde.

iv.Ethene to formaldehyde.

v.Sodium Benzoate to Benzene.

OR

What happens when

a. Ethyne gas is allowed to pass over red hot iron tube.

b. Calcium carbide is treated with water.

c. Propene is treated with dilute KMnO4.

d. Benzene is treated with chlorine in presence of UV light.

e. Phenol is treated with heated zinc dust.

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CBSE Class XI Chemistry Unit Test (First Term)

1

Express the following in the scientific notation:

a) 0.000456 b) 500.0

(1)

2

Name the experiment which is used to find the charge of an electron & what is the charge of an electron?

(1)

3

What are the drawbacks of Rutherford’s atomic model?

(1)

4

Round up the following up to three significant figures.

a) 46.216 b) 10.4107 c) 0.04597 d) 2808

(2)

5

Calculate the number of atoms in the following;

a) 52 moles of Ar b) 52g of He.

(2)

6

What is the SI unit of mass? How is it defined?

(2)

7

State law of multiple proportion with an example.

(2)

8

The density of 3M solution of NaCl is 1.25g/ml. Calculate molality of the solution.

(2)

9

Define isobars with examples.

(2)

10

Mention the two developments which played a major role in the formulation of Bohr’s model of an atom.

(2)

11

The atomic number and mass number of Calcium are 20 & 40 respectively. Find out the number of electrons, protons and neutrons in a Ca2+ ion.

(2)

12

a) How many seconds are there in 3 days?

b) A jug contains 5L of milk. Calculate the volume of milk in m3.

(3)

13

Calculate the concentration of HNO3 in moles per litre in a sample which has density 1.41g/ mL & the mass percent of nitric acid in it being 69%.

(3)

14

A compound contains 4.07% Hydrogen, 24.27 carbon and 71. 65% chlorine. Its molar mass is 98.96g. What is the empirical formula of the compound?

(3)

15

Write notes on Thomson’s plum pudding model of atom with its important features.

(3)

16

What are the conclusions drawn by Rutherford in his gold foil experiment?

(3)

17

i) Define limiting reagent.

ii) 50.0kg of N2 (g) and 10.0kg of H2 (g) are mixed to produce NH3 (g). Calculate the NH3(g)

produced. Identify the limiting reagent in this reaction.

(1+4)

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CBSE Chemistry Class 11 (Mid Term Exam Model Paper)

CLASS:XI CHEMISTRY

Duration: 3 hrs Maximum marks: 70

General Instructions:

All questions are compulsory.

i)Marks for each question are indicated against it.

ii)Question numbers 1 to 8 are very short answer questions and carry 1 mark each.

iii)Question numbers 9 to 18 are short answer questions and carry 2 marks each.

iv)Question numbers 1 9 to 27 are also short answer questions and carry 3 marks each.

v)Question numbers 28 to 30 are long answer questions and carry 5 marks each.

vi)Use logarithm tables if necessary. Use of calculator is not allowed.

Questions:-

1 Calculate the number of moles in 14g of N2 molecule. (1)
2 What would be the IUPAC and symbol for the elements with atomic numbers 121 and 113. (1)
3 Draw the Lewis dot structure of Nitrite ion (NO2). (1)
4 What do you meant by bond length? (1)
5 Define coefficient of viscosity. What is its S.I. unit? (1)
6 Calculate the oxidation number of phosphorous in H3P2O7and Au in HAuCl4. (1)
7 How the presence of H ions be confirmed in ionic hydrides? (1)
8 What do you understand by the term hydrogen economy ? (1)
9 Chlorine is prepared in the laboratory by treating MnO2 with aqueous HCl according to the reaction:

clip_image001[4]4HCl(aq) + MnO2 (s) 2H2O (l) + MnO2(aq) + Cl2(g)

How many grams of HCl react with 5.0 g of MnO2?

(OR)

clip_image002[6]Calcium carbonate reacts with aqueous HCl to give CaCl2 and CO2 according to the reaction, CaCO3 (s) + 2HCl(aq) CaCl2 (aq) + CO2 (g) +H2O (l).

What mass of CaCO3 is required to react completely with 25ml of 0.75 M HCl?

Atomic mass of Mn=25,Ca=20 Read more…

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Fast Review – Chemical Bonding and Molecular Structure

1. The attractive force which holds together the constituent particles (atoms, ions or molecules) in chemical species is known as chemical bond.
2. Tendency or urge atoms of various elements to attain stable configuration of eight electrons in their valence shell is cause of chemical combination.
3. The principle of attaining a maximum of eight electrons in the valence shell or outermost shell of atoms is known as octet rule.
4. Electronic Theory: Kossel-Lewis approach to chemical Bonding: Atoms achieve stable octet when they are linked by chemical bonds. The atoms do so either by transfer or sharing of valence electrons. Inner  shell electrons are not involved in combination process.
5. Lewis Symbols or electron dot symbols: The symbol of the element represents the whole of the atom except the valence electrons  (i.e. nucleus and the electrons in the linear energy shells). The valence electrons are represented by placing dots (.) or crosses (x) around the symbol.
6. Significance of Lewis Symbols: The Lewis symbols indicate the number of
electrons in the outermost or valence shell which helps to calculate common or group valence.
7. The common valence of an element is either equal to number of dots or
valence electrons in the Lewis symbol or it is equal to 8 minus the number of
dots or valence electrons.
8. The bond formed by mutual sharing of electrons between the combining
atoms of the same or different elements is called a covalent bond.
9. If two atoms share one electron pair, bond is known as single covalent bond and is represented by one dash (–).

Read more…

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